Without Misty there to catch Psyduck, Brock or Ash may have opted to take it instead, since it seemed to be quite attached to the group when they first met.- She can do voice impressions of Pikachu, Squirtle, and Psyduck. The relation between the two is unclear.EXQUARE / Platinum 2 14LP / 104Win 103Lose Win Rate 50% / Sett - 38Win 25Lose Win Rate 60%, Volibear - 6Win 7Lose Win Rate 46%, Renata Glasc - 6Win 5Lose Win Rate 55%, Lux - 5Win 4Lose Win Rate 56%, Karma - 3Win 3Lose Win Rate 50%One of Misty's signature Pokémon, Psyduck, was caught entirely by accident when she tripped and dropped a Pokéball, which the Psyduck used to catch itself out of sheer stupidity. Although Manaphy resembles Phione, it is also quite different. Rumored to migrate across the oceans and visit Hisui's coastal waters only rarely. This Pokémon is easily affected by its environment. When Ash first received Pikachu, he wouldn't do anything he was.